Highly diastereoselective synthesis of decalin skeletons with quaternary carbon centers via the tandem oxy-Cope/ene/Claisen reaction.
نویسندگان
چکیده
The highly diastereoselective cascade sequence of three successive thermal pericyclic reactions of 1,2-divinylcyclohexanol allyl and propargyl ethers is described. This novel tandem process provides an efficient synthesis of sesqui- and diterpenoid skeletons having a quaternary carbon at C9. [reaction: see text]
منابع مشابه
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عنوان ژورنال:
- Organic letters
دوره 4 8 شماره
صفحات -
تاریخ انتشار 2002